The answer is: 114

Psalm 145:18 - The term "prayer" appears 114 times in the KJV, highlighting its significance in a believer's life. Throughout scripture, prayer serves as a vital means of communication with God, exemplified by Jesus in Matthew 6:9-13 with the Lord’s Prayer. This unified theme underscores spiritual intimacy and reliance on divine guidance.

The significant presence of the word "prayer" in the Bible, with its 114 mentions, isn’t just a fascinating numerical fact; it really emphasizes the centrality of conversation with the Divine in the lives of believers. From the robust prayer life of the Old Testament prophets to Jesus setting the perfect example of prayer in the New Testament, the role of prayer emerges as a connective thread woven throughout sacred scripture.

Consider Elijah, who called upon God to bring fire from heaven, showcasing prayer's power in crucial moments (1 Kings 18:37-38). Then there’s Daniel, whose habit of regular prayer was so deeply ingrained that he continued despite the king’s decree (Daniel 6:10), revealing that true to its core, prayer is often about persistence and the courage to uphold one’s convictions.

Interestingly, many verses underscore that it's how one prays that's essential, not merely the act itself. Philippians 4:6 encourages believers to make requests known to God with thankfulness, reminding us of the attitude we should carry into our prayers. This sense of gratitude sets the tone for maintaining a positive outlook.

On top of that, the book of Psalms offers a rich library of prayers that connects believers to individual expressions of life’s triumphs and struggles. It’s the book where prayers range from deep lament to joy-filled praise, showcasing just how prayer can be a profoundly personal reflection of the human condition. So, the next time you hear someone share a prayer request or a heartfelt prayer, think about that centuries-old tradition of seeking the one higher than ourselves.